| Guia docent Escola Tècnica Superior d'Enginyeria Química |
català |
| Nanociència i Nanotecnologia (2010) |
 Assignatures |
| QUÍMICA MACRO I SUPRAMOLECULAR |
| Continguts |
| DADES IDENTIFICATIVES | 2010_11 |
| Assignatura | QUÍMICA MACRO I SUPRAMOLECULAR | Codi | 20635258 | |||||
| Ensenyament |
|
Cicle | 2n | |||||
| Descriptors | Crèd. | Tipus | Curs | Període | ||||
| 5 | Optativa | Únic anual |
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| Competències | Objectius d'aprenentatge | Continguts |
| Planificació | Metodologies | Atenció personalitzada |
| Avaluació | Fonts d'informació | Recomanacions |
| Tema | Subtema |
| Tema 1. | From molecular chemistry to supramolecular chemistry. Non-covalent interactions. |
| Tema 2. | Complementarity, induced fit, allosterism and cooperativity. Receptors and carriers. Dynamic processes: kinetics vs. thermodynamics. |
| Tema 3. | Ion recognition. Crown ethers, cryptands, cyclophanes, other receptors. Chiral recognition. |
| Tema 4. | A view of the hydrophobic effect. Hydrophobic interactions in molecular recognition. |
| Tema 5. | Supramolecular catalysis. Basic principles. Acceleration and turnover. Transition state recognition. Enzyme models. |
| Tema 6. | Confinement effects in catalysis. Micelles, vesicles, capsules. Catalytic antibodies and polymer imprinting. Autocatalysis: self-replicating systems. |
| Tema 7. | Molecular recognition of bio-molecules-1. Amino acids, peptides, proteins. Ligand-protein and protein-protein interactions. |
| Tema 8. | Molecular recognition of bio-molecules-2. Nucleobases, nucleotides and nucleic acids. DNA-ligand interactions. Intercalation. Recognition of carbohydrates. |
| Tema 9. | Self-assembly and self-organization. |
| Tema 10. | Self-assembly in synthetic systems. |
| Tema 11. | Dynamic combinatorial chemistry and supramolecular chirality. |
| Tema 12. | Molecular materials and devices. |
| Tema 13. | Hierarchical self-assembly. Monolayers and multilayers. Liquid crystals. Thermotropic and lyotropic systems. Mesophases. Phase diagrams. LC displays. |
| Tema 14. | Charge-transfer systems. Organic insulators, semiconductors, and conductors. Non-linear optics. Concepts. Dipolar and octupolar molecules. NLO devices. |
| Tema 15. | Experimental methods in supramolecular chemistry. Stoichiometry and binding constant. NMR titrations. Other methods. Aggregation and transport. |
| Tema 16. | Photo physics of Supramolecular Systems. Basic Principles. Photo physics of Supramolecular Advanced Concepts. |
| Tema 17. | Applications of luminescent supramolecular systems. Hetero Supramolecular Chemistry. Supramolecular systems for light to electric energy conversion. Part 1. Supramolecular systems for light to electric energy conversion. Part 2. Supramolecular Organic Field Effect Transistors. Future perspectives on Functional Supramolecular Devices. |
