IDENTIFYING DATA 2013_14
Subject (*) NANOSTRUCTURED POLYMERIC MATERIALS Code 20705216
Study programme
Nanoscience, Materials and Processes: Chemical Technology at the Frontier
Cycle 2nd
Descriptors Credits Type Year Period
4.5 Optional Only annual
Language
Anglès
Department Analytical Chemistry and Organic Chemistry
Coordinator
SERRA ALBET, MARIA ANGELS
E-mail joseantonio.reina@urv.cat
angels.serra@urv.cat
Lecturers
REINA LOZANO, JOSÉ ANTONIO
SERRA ALBET, MARIA ANGELS
Web
General description and relevant information The goal of the subject is to introduce the student to synthesis, characterization and applications of new polymeric architectures and nanostructured materials.

Competences
Type A Code Competences Specific
 A1 A1.1. Successfully studying and learning about the chosen research ambit: evaluating the technical and scientific importance, the technological potential and the viability of the nanoscience, design, preparation, properties, processes, developments, techniques and applications of materials.
 A8 A2.2. Critically evaluating the results of research in the field of nanotechnology, materials and products and process design.
Type B Code Competences Transversal
 B9 B1.1. Communicating and discussing proposals and conclusions in specialized and non-specialized multilingual forums in a clear and unambiguous manner.
 B16 B4.2 Learning autonomously and by using initiative.
 B19 B5.3. Applying critical, logical and creative thought in a research and innovative context.
Type C Code Competences Nuclear
 C1 Have an intermediate mastery of a foreign language, preferably English

Learning outcomes
Type A Code Learning outcomes
 A1 A1.1 Have a broad knowledge of the field of nanostructured polymeric materials: their synthesis, structural characteristics, characterisation techniques and applications.
 A8 A2.2 Can formulate knowledge on genomics, metabolomics and proteomics.
Type B Code Learning outcomes
 B9 B1.1 Can intervene effectively and transmit relevant information.
B1.1 Plan their communication: generate ideas, seek information, select and order information, make schemes, decide on the audience and the aims of the communication, etc.
B1.1 Prepare and deliver structured presentations, complying with the requirements.
B1.1 Draft documents with the appropriate format, content, structure, language accuracy, and register, and can illustrate concepts using the correct conventions: format, headings, footnotes, captions, etc.
B1.1 Use language that is appropriate to the situation.
B1.1 Are aware of the strategies that can be used in oral presentations (audiovisual support, eye contact, voice, gesture, timing, etc.).
 B16 B4.2 Ask the appropriate questions for solving doubts or open questions, and search for information with criteria.
B4.2 Select a procedure from among the possibilities suggested by the lecturer.
 B19 B5.3 Follow a logical method for identifying the causes of a problem.
Type C Code Learning outcomes
 C1 Express opinions on abstract or cultural topics in a limited fashion.
Explain and justify briefly their opinions and projects.
Understand instructions about classes or tasks assigned by the teaching staff.
Understand routine information and articles.
Understand the general meaning of texts that have non-routine information in a familiar subject area.
Write letters or take notes about foreseeable, familiar matters.

Contents
Topic Sub-topic
Topic 1. Introduction to the field of polymers.
Basic terminology.
Polymeric architectures.
Polymerization methods.
Characterization and properties.
Topic 2. Copolymers
Types.
Block copolymers: self-assembly.
Micelles.
Micro-and nanoencapsulation.
Topic 3. Brush Polymers Synthesis.
Grafting from.
Grafting onto.
Characterization.
Applications
Topic 4. Dendrimers.
Synthetic pathways and examples.
Characterization.
Applications.
Topic 5. Hyperbranched polymers.
Synthetic pathways and examples.
Characterization.
Applications
Topic 6. Linear-dendritic polymers. Synthetic pathways and examples.
Characterization.
Applications
Topic 7. Star polymers.
Synthetic pathways and examples.
Characterization.
Applications
Topic 8. Top-down approach to nanostructured materials.
Types.
Preparation.
Characterization.
Applications.
Topic 9. Bottom-up approach to nanostructured materials.
Types.
Preparation.
Characterization.
Applications.
Topic 10. Nanostructurated flame retardant materials
Introduction to flame-retardancy.
Phosphacene, carborane and silsesquioxanes based systems.
Topic 11. Introduction to liquid crystals.
Terminology.
Mesophases.
Characterization techniques.
Structure-assembly relationships.
Topic 12. Liquid crystal polymers. Types.
Charaterization.
Structural applications and applications for advanced technologies.

Planning
Methodologies  ::  Tests
  Competences (*) Class hours
Hours outside the classroom
(**) Total hours
Introductory activities
1.7 0 1.7
Lecture
B19
C1
34 57.8 91.8
Presentations / expositions
A8
B9
B16
C1
8 8 16
Personal tuition
B9
1 0 1
 
Objective short-answer tests
A1
B16
2 0 2
 
(*) On e-learning, hours of virtual attendance of the teacher.
(**) The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies
  Description
Introductory activities Presentació de l'assignatura i els continguts i metodología
Lecture Exposició dels continguts teòrics de l'assignatura
Presentations / expositions Presentació oral dels resultats d'un article cientítfic de la literatura recent per part dels estudiants i discussió crítica amb els professors.
Personal tuition Consulta de dubtes a nivell individual

Personalized attention
Description
Consulta de dubtes a nivell individual

Assessment
Methodologies Competences Description Weight        
Presentations / expositions
A8
B9
B16
C1
Exposició oral i contesta de preguntes sobre el tema exposat 50%
Objective short-answer tests
A1
B16
Resposta a qüestions relacionades amb els continguts teòrics de l'assignatura. 50%
Others  
 
Other comments and second exam session

2a convocatòria: Igual que la primera convocatòria.


Sources of information

Basic G.R. Newkome, C.N. Moorefiled, F. Vögtle, Dendrimers and Dendrons, Wiley VCH, Weinheim, 2001
A. Donald, A. Windle, S. Hanna , Liquid Crystalline Polymers, 2on ed. Cambridge Univ. press, Cambridge, 2006
K. Matyjaszewski, Y. Gnanou, L. Leibler, Macromolecular Engineering, eds. Vol 1-4, Wiley-VCH, Weinheim, 2007
Ch. Kumar, Polymeric Nanomaterials, ed. Wiley-VCH, Weinheim, 2011
R.C. Advincula, W. J. Brittain, K.C. Caster, J. Rühe, Polymer Brushes, Wiley-VCH, Weinheim, 2004
J-L. Halary, F. Lauprêtre, L. Monnerie, Polymer Materials, Wiley, Hoboken, 2011

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(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.