| Educational guide Faculty of Oenology |
english |
| Bachelor's Degree in Biotechnology (2009) |
 Subjects |
| THERMODYNAMICS AND KINETICS |
| Contents |
| IDENTIFYING DATA | 2018_19 |
| Subject | THERMODYNAMICS AND KINETICS | Code | 19204111 | |||||
| Study programme |
|
Cycle | 1st | |||||
| Descriptors | Credits | Type | Year | Period | ||||
| 4 | Compulsory | Second | 2Q |
|||||
| Competences | Learning outcomes | Contents |
| Planning | Methodologies | Personalized attention |
| Assessment | Sources of information | Recommendations |
| Topic | Sub-topic |
| Review of thermodynamic concepts | State equations Thermodynamic relations and functions Ideal gases Mass and energy balances. 1st, 2nd and 3rd laws. Gibbs energy and chemical potential. |
| Transformations of matter | Change and phase balance. Pure substances. Multicomponent systems. Phase diagrams |
| Solutions | Composition, mixing magnitudes, ideal and diluted ideal solutions. Deviation from ideal behavior |
| Reminder of concepts of chemical kinetics | Reaction rate: rate equation, reaction order, rate constant Mechanisms of reaction: elementary stage, simple reaction, complex reaction. Apparent constant, pseudoordre |
| Analysis of kinetic data | Methods of determining reaction orders. Method of integration by simple reactions. Pseudo-order reaction. Apparent constant. Experimental techniques for the determination of reaction rates. |
| Influence of temperature on the rate of reactions | Arrhenius equation. Arrhenius Theory. Activated complex and frequency factor. Molecular interpretation. |
| Kinetic treatment of complex reactions | Arrhenius equation. Arrhenius Theory. Activated complex and frequency factor. Molecular interpretation. |
| Mechanisms of reaction | Complexity of mechanisms. Approximation of the determining step of a reaction. Steady state approach. Examples of known mechanisms. Catalytic mechanisms. Enzymatic catalysis. |
